Solvent-tuned magnetic exchange interactions in Dy2 systems ligated by a μ-phenolato heptadentate Schiff base
نویسندگان
چکیده
منابع مشابه
Single molecule magnetism in a μ-phenolato dinuclear lanthanide motif ligated by heptadentate Schiff base ligands.
The heptadentate Schiff base ligand, 2-(2-hydroxyphenyl)-1,3-bis[4-(2-hydroxyphenyl)-3-azabut-3-enyl]-1,3-imidazoline (H(3)api), yields [Ln(2)api(2)] species when combined with lanthanide salts under basic conditions. A survey of the magnetic properties of this dinuclear lanthanide motif (Ln = Gd, Tb, Dy, Ho) has identified weak magnetic exchange, antiferromagnetic in nature for the isotropic g...
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ژورنال
عنوان ژورنال: RSC Advances
سال: 2019
ISSN: 2046-2069
DOI: 10.1039/c9ra08754k